Amazon.com just notified me that the 22-movie blu-ray set (and book of posters) has shipped and will be here Monday.
Favorites, songwise: Goldfinger, You Only Live Twice, Live and Let Die, The Spy Who Loved Me, A View to a Kill, The Living Daylights, License to Kill, Goldeneye, Casino Royale (Daniel Craig version!, though Bacharach's silly score for the 1967 movie is fun).
I also love Blondie's rejected theme for For Your Eyes Only.
http://www.youtube.com/watch?v=Y2Y-hCydiXA
I have MANY favorite tracks from all the movies, but the one that sticks out the most right now (I'm at work, sneaking this in

) is "Hercules Takes Off" from The Living Daylights.
http://www.youtube.com/watch?v=35DP_0zTwK0
My first electronica massive (mega-rave) in the 90's was at a ski resort that featured many live performances by musicians such as Underworld, The Orb, The Chemical Brothers, etc.... and then it came time for Orbital, with THIS music playing to a dark stage, mounting to a defeaning crescendo before the lights, lasers, and the Hartnoll Brothers took over: (Capsule in Space, from You Only Live Twice)
http://www.youtube.com/watch?v=seJTKp6WX-g 
!!!!